These last longer and look beautiful, when made out of plaster of Paris, the pot can be decorated with cute colors and designs that speak to the person. Decorating your small cozy places with these stunning sculptures is indeed a mindblowing idea.ĭid you know? More interestingly, there’s also an artist that makes sculptures of pregnant bellies out of plaster of Paris for mothers-to-be and beautifully decorates them. These can create memories which last a life time. Sculptures can be extremely personalized by making impressions of hands or footprints. This is another plaster of Paris art and craft idea for adults. You can make it creative and colorful using acrylic paints.ĪLSO READ – Simple Origami Crafts for Kids to Enhance Their Creativity The added benefit of this is the fact that you don’t need the revolving potter’s wheel. A vase where you can put in fresh flowers and flaunt it in front of every guest how you made it. Plaster of Paris Art and Craft Ideas Plaster of Paris Art and Craft Ideas for AdultsĮvery kid dreams of having a self-made vase at home.
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Pewter Blue HEX #8BA8B7 RGB 139, 168, 183 RGB percentage 55%, 66%, 72% CMYK 24, 8, 0, 28 HSL 196°, 20%, 65%Ī bright primary blue, Blue Ryb is one of the three traditional shades of blue used to mix other colors. It has a timeless quality that will bring elegance and sophistication to any room. Pewter blue is a dark, muted shade that carries hints of navy and gray. It’s great for making something stand out. Similar to Electric Blue but more intense, Neon Blue adds energy and life to any design. Ruddy Blue HEX #76ABDF RGB 118, 171, 223 RGB percentage 46%, 67%, 87% CMYK 47, 23, 0, 13 HSL 212°, 59%, 67%Ī bright sky-blue with hints of purple, Cornflower Blue brings to mind the beauty of summer days spent outdoors.Ĭornflower Blue HEX #6495ED RGB 100, 149, 237 RGB percentage 39%, 58%, 93% CMYK 59, 37, 0, 7 HSL 219°, 79%, 66% Use it to evoke feelings of calmness, confidence, and relaxation. Ruddy blue is a slightly desaturated shade of greenish-blue that exudes a sense of freshness and serenity. From the classic blue to the soothing azure and the mysterious navy, the blue color family offers a plethora of options that can evoke a multitude of emotions and moods.ĭive into our detailed shades of blue list, each with its unique names, HEX, RGB, and CMYK codes.īlue HEX #0000FF RGB 0, 0, 255 RGB percentage 0%, 0%, 100% CMYK 100, 100, 0, 0 HSL 240°, 100%, 50%Ĭombining grays and blues, Medium Slate Blue adds depth and complexity to any design. It has a rich history and a wide range of use cases in art, design, and fashion. Whether you're looking to create a soothing bedroom or a professional office, blue shades can help you achieve the desired effect.īlue (HEX #0000FF) is an enchanting color, often associated with tranquility, stability, and depth. Teal is often used in interior design to add a pop of color to neutral spaces, or in fashion to create a bold statement.īlue shades are an excellent choice for creating a calming and peaceful atmosphere. It is a versatile color that can be used to create a soothing or energizing atmosphere for any context. Teal is a unique blue-green shade that combines the calmness of blue with the vibrance of green. Baby blue is a pale, gentle shade that is commonly used in baby products and nurseries. Sky blue is a light and soft shade that evokes a sense of serenity. Royal blue is a bright, bold shade that is often associated with royalty, luxury, and elegance. Navy blue is a dark blue that exudes sophistication and professionalism, making it a popular choice for corporate settings. Some common blue shades include navy blue, royal blue, sky blue, baby blue, and teal. Shades of blue can evoke different emotions and have distinct meanings, depending on their tone and intensity. 4K at 60fps requires iPod Touch (7th generation), iPhone SE (2nd generation), iPhone 7 or later, iPad (6th generation) or later, iPad mini (5th generation), iPad Air 3 or later, or 10.5-inch Ipad Pro or later.IPhone/iPad: Apple iMovie 2.3.1: System requirements 4GB of RAM (but the more RAM the better). Mac: Apple iMovie 10.2.1: System requirements But whether that proves to be the case, we’ll have to wait and see. This isn’t inconceivable considering the contrast between the latest macOS and iOS updates, not to mention the increasingly advanced cameras on iPhone. Of course, there’s always a chance that Apple is looking to focus its iMovie efforts on the future of its iOS apps. And there appears to be no sign that this will change any time soon, which means iMovie risks falling behind the times. IMovie’s biggest downfall is the lack of significant updates for Mac. When it comes to splicing, trimming, arranging footage, and soundtracks, it works as you’d expect and it’s easy to master-making it perfect for beginners. At the same time, its simplicity isn’t necessarily a bad thing. The best thing about iMovie is that it’s free, although the price is reflected in its limitations. This is great for making the most of your footage when filming conditions were less than perfect. Whilst neither are perfect, they do a pretty good job of stabilizing your footage and dampening any background noise on the audio. Two tools that we’ve found to be particularly useful are the shake and noise reduction tools. There are also options to slow down and speed up the playback of your clips, essentially giving users the power of slow motion, which is always fun. Moreover, you can use the Match Color feature to ensure the overall look of your video is consistent as well as adjust the white balance of your footage. Well, fortunately for you, there are customizable features that enable you to alter the contrast, saturation, and temperature. Preset effects are all well and good, but maybe you want more control over the final look of your footage. Apple iMovie review: Backgrounds, transitions, and effectsĪs well as preloaded effects, there are some handy customizable tools as well (Image credit: Apple) It’s worth noting that once you’ve started a project, you can’t switch between the Movie and Trailer editing modes. However, if you’re more adept with editing, you’ll have no trouble with the Movie option, and might even prefer it. Whilst there’s a novelty factor in the end result, creating an iMovie trailer is quick, easy, and fun. IMovie gives you an Outline where you can title your movie and add credits, a Storyboard that acts as a roadmap for the final product, and a Shot list with suggestions of what kind of footage you should include. There are 29 Trailer templates in total, all of which are themed to suit a different genre, from adventure and action to romance and comedy. In essence, the tool provides you with a template, which includes ready-made titles, effects, and placeholders. It enables you to quickly turn raw footage into a finished video without needing any knowledge or experience in video editing. If you opt for Movie, you get complete control over the editing of your footage, whereas Trailer does all the hard work for you. When you create a new project in iMovie, you’ll be asked if you want to create a Movie or a Trailer. IMovie comes with Trailer templates, which are great for quickly producing fun videos (Image credit: Apple) Narrator ( ナレーション, Narēshon) Voiced by: Misako Tomioka (Japanese) Brianna Roberts (English) Production Nevertheless, she starts to cosplay after some encouraging from the others. While Shinju secretly wishes to cosplay herself, she fears falling short of her sister's high standards. She is also skillful at using a computer, processing and uploading the images she takes. When Sajuna cosplays, Shinju assumes the role of a photographer, using a camera borrowed from their father. Shinju is close to her sister and holds her in high regard. However, despite her imposing physique, she is remarkably timid. She is 178 cm tall and has voluptuous curves, because of which she is sometimes mistaken for an adult. Shinju is a junior high school student, but compared to her sister's petite figure, she is so big that she could almost fit into Wakana's uniform. Shinju Inui ( 乾 心寿, Inui Shinju) Voiced by: Hina Yōmiya (Japanese) Jad Saxton (English) Sajuna's younger sister. Sajuna cherishes her younger sister Shinju and does all she can to make her happy. On the other hand, she is outspoken and proactive, similar to Marin, who will go to great lengths to achieve her goals. However, despite being a year older than Wakana and Marin, Sajuna's youthful petite appearance was mistaken for a junior high or elementary student. She is a sophomore at an all-girls private high school. Sajuna Inui ( 乾 紗寿叶, Inui Sajuna) Voiced by: Atsumi Tanezaki (Japanese) Risa Mei (English) A cosplayer who presents herself under the nickname of "Juju" ( ジュジュ). She usually lives alone as her mother died when she was a child and her father is often away due to work. She continually does whatever she can to invite him to different places and spend time with him. After a series of successful cosplay, Marin grows closer to Wakana and eventually realizes she is in love with him. Marin is shown to dislike overly critical people who judge others based on their interests, prompting her to reject the advances of a boy who made fun of her liking anime. Marin Kitagawa ( 喜多川 海夢, Kitagawa Marin) Voiced by: Hina Suguta (Japanese) Amanda Lee (English) A beautiful girl, archetype of a gyaru, notable for her warmth, friendliness, positivity, and outgoing nature. He grew more confident with each project, and through their collaboration, Wakana found a sense of belonging in the cosplay community that he had never experienced before. Thanks to Marin's encouragement and support, Wakana stepped out of his comfort zone and embraced his love for crafting. Likewise, he hid his doll-making hobbies and had no friends until he met Marin. Wakana has a large physique and is over 180 cm tall, but he has low self-esteem and is reclusive due to a bitter memory of being criticized by his female classmate, who thought a boy should not be playing with girl dolls. Being an orphan, he was raised by his grandfather, a craftsman of hina dolls, who also inspired him to become a kashira-shi ( 頭師), a craftsman who makes the head of a hina doll. Working together, they create unique and beautiful costumes showcasing their talents and true selves.Ĭharacters Wakana Gojo ( 五条 新菜, Gojō Wakana) Voiced by: Shōya Ishige, Tomoyo Takayanagi (young) (Japanese) Paul Dateh, Jack Britton (young) (English) A first-year high school student. With Marin's unwavering support, Wakana steps out of his seclusion and begins to gain confidence. However, when his classmate Marin Kitagawa discovers his talent, she sees beyond his apparent idiosyncrasies and encourages him to create cosplay costumes. Wakana Gojo's passion for crafting hina dolls causes him to hide his interests due to social trauma. A sequel has been announced.īy May 2023, the manga had 9.3 million copies in circulation. An anime television series adaptation produced by CloverWorks aired from January to March 2022. It began serialization in Square Enix's Young Gangan in January 2018, and has been compiled into eleven volumes as of March 2023. "That Bisque Doll Falls in Love") is a Japanese manga series written and illustrated by Shinichi Fukuda. My Dress-Up Darling ( Japanese: その 着せ替え人形 ( ビスク・ドール )は恋をする, Hepburn: Sono Bisuku Dōru wa Koi o Suru, transl. Tokyo MX, GYT, GTV, BS11, ytv, Mētele, AT-X Thanks, it's ironic that lagnut was the person I learned that trick from (the game before-I got completely owned). It seems to be a "take a genre that was popular 15 years ago, make a modern shitty version of it, hope that everybody forgot that genre existed so it looks fresh and exciting" kind of said: Nice way to clear the path to your fellow soldier. What happened to the red soldier on the right? The camera just zooms off of him. Maybe if he had actually made, you know, graphics? Maybe then I'd like it. And it's crummy "this game is using a 3D engine even though we were too lazy to make proper 3D graphics and it probably shouldn't be" makes it so visually confusing, half the time you get shot you're thinking, "wait, that guy wasn't behind cover? But it looks like he is- shift the camera a bit- oh." Seriously? I will never understand people's love for this game.Įven if you think that style of gameplay was fun, the game is so lazy and bland. The story was so goddamned insultingly said: Frozen Synapse is the best game. I'm about 4-6 hours into it, but I've seen enough to be able to HIGHLY RECOMMEND this to anyone into said: Defender's Quest - Valley of the Forgotten If anyone is getting into this and needs party creation tips, let me know. They really need a proper documentation for what influences which weapon type etc. I had to restart the game like 4-5 times until I got my characters just right. Special moves are tied to weapons and are no longer luck-triggered. Better character system (5 races, 7-8 classes, traits). So what's improved compared to the first part? Outdoors areas. Sounds strange, but don't knock it until you try it. This makes for pretty exciting action-y battles, while still retaining a strategic undertone. Movement is grid based, but in real time. An exemplary approach to making sequel.įor those who don't know, Grimrock is a first person party-based RPG. It fixes what was broken, extends where it was lacking and otherwise leaves the winning formula intact. I'm finally deep enough into the sequel to post this. I've hinted that I'm a Grimrock fan a few times before. Sleeping Dogs - Zodiac Tournament Trailer – 01:23 Now, I just need to grind up a bit more and I'll be ready to start the Zodiac Tournament DLC - a riff on Enter The Dragon, complete with 70s music and visuals. My chief gripe is that it isn't particularly comfortable to play with a mouse/keyboard - I've a feeling that a controller would do wonders for the kung-fu fighting (not to mention the driving and action hijack sequences - I'm pants when driving with my left hand). Hong Kong provides an interesting and exotic, yet vaguely familiar backdrop, which is also a refreshing change from the norm. The fact that you play an undercover cop is a welcome change from the standard "be a gangsta and fuck people's shit up" fare, typical of the genre and adds some nice depth to the story. I like the story, I like the characters, I like the setting and I like the gameplay. It's, hands-down, the best GTA-style sandbox game I've played so far (mind you, I've not had a go at GTA V, yet). Sounded fun, checked it out and I wasn't disappointed. I originally came across this one on El Reg, as part of the "games of 2012 you probably missed" list, or some such. I got the DLCs for this one lately, so I've decided to replay the main story and then have a go at those. Another mode allows you to drive cooperatively (up to four players) in a single race. Next Next post: Need for Speed: Most Wanted (Black Edition) (Europe) PS2 ISO. In Pursuit Knockout everyone starts as a civilian car, but the last one at the end of the first lap becomes a cop and needs to cause as much damage as possible to the other speeders. Previous Previous post: Need for Speed ProStreet (Europe) PS2 ISO. To become the civilian car, you have to tag it and then try to fend off the cops as long as possible until you are tagged again by other players. Pursuit Tag is a race of one civilian car against cop cars. Xenosaga Episode III (PCSX2 Memory Card Save File) (160) 05. Harvest Moon: Save the Homeland Start with all tools, belongings, and 99 seeds. God of War (PS2 - PAL) 47 save points (580) 03. Up to eight players can race together, in the Pursuit Tag or Pursuit Knockout modes, with a few variations. Ratchet and Clank 3 - Challenge Mode PCSX2 Memory Card Save (48) 02. The PC, PS3 and Xbox 360 versions offer online multiplayer, missing from the PS2, GC and Xbox releases. Other features include the possibility to form your own crew, more detailed sculpting features, drifting races (introduced in NFS:U and replaced by drag races in NFS:MW) and the new car classes. A special Collectors Edition version of the title was developed for PlayStation 2, Windows and Xbox 360, and included additional content including new cars. The career mode offers complete freedom in a city with a story mode supported by FMV cutscenes, as featured in Need for Speed: Most Wanted, but now also set in the Carbon Canyon, where racers duel for territory in the city below. Many of them have been featured in previous installments, but there is a new selection and this year's edition introduces powerful muscle cars such as the Ford Mustang and Dodge Charger. The 2006 game in the Need for Speed series is an evolution of the gameplay introduced in the previous games. Need for Speed Carbon immerses you in the worlds most dangerous and adrenaline-filled form of street racing, which begins in the city and ends in the. Need for Speed: Undercover is a Racing video game published by Electronic Arts released on November 17th, 2008 for the PlayStation Portable. You can also play this game on your mobile device. Download Need for Speed - Carbon - Collector's Edition ISO to your computer and play it with a compatible emulator. Enhancements are still unlocked gradually, but the cars have now been divided over different tiers. JOGO PLAYTATION 2 ISO Addeddate 21:52:23 Identifier need-for-speed-carbon-collectors-edition Scanner Internet Archive HTML5 Uploader 1.6.4. Need for Speed: Undercover (USA) PSP ISO Download. Need for Speed - Carbon - Collector's Edition ISO download is available below and exclusive to. Sulfur tetrafluoride is the premier example of a molecule with the disphenoidal molecular geometry (see image at upper right). Examples of triatomic molecules for which VSEPR theory predicts a linear shape include BeCl2 (which does not possess enough electrons to conform to the octet. The four atoms in motion act as a lever about the central atom for example, the four fluorine atoms of sulfur tetrafluoride rotate around the sulfur atom. Thus, the 19F NMR spectrum of SF 4 (like that of PF 5) consists of single resonance near room temperature. The angle between the axial ligands and the equatorial ligands is 90° whereas the angle between the two equatorial ligands themselves is 120°.ĭisphenoidal molecules, like trigonal bipyramidal ones, are subject to Berry pseudorotation. Typically the bond distance to the apical ligands is longer than to the equatorial ligands. A separate pair of ligands is situated orthogonal to the axial ligands. doi: 10.1021/ed083p336.2.Compounds with disphenoidal geometry (See-Saw Geometry) have two types of ligands, one pair related by 180° often called axial ligands. "Mechanisms that Interchange Axial and Equatorial Atoms in Fluxional processes: Illustration of the Berry Pseudorotation, the Turnstile and the Lever Mechanisms via animation of transition state normal vibrational modes". "Dynamic nuclear magnetic resonance study of fluorine exchange in liquid sulfur tetrafluoride". Discover the place of tetrahedrons in the valence shell electron repulsion theory through examples of tetrahedral. "The Trigonal Bipyramid Geometry (SN = 5) (VSEPR Part 4)" (PDF). The following compounds and ions have disphenoidal geometry: Sulfur tetrafluoride is the premier example of a molecule with the disphenoidal molecular geometry (see image at upper right). This exchange of positions results in similar time-averaged environments for the two types of ligands. The ideal angle between the axial ligands and the equatorial ligands is 90° whereas the ideal angle between the two equatorial ligands themselves is 120°.ĭisphenoidal molecules, like trigonal bipyramidal ones, are subject to Berry pseudorotation in which the axial ligands move to equatorial positions and vice versa. Typically the bond distance to the axial ligands is longer than to the equatorial ligands. In an SF4 molecule, two of the S-F bonds are situated across from one another in the equatorial plane. The equatorial pair of ligands is situated in a plane orthogonal to the axis of the axial pair. SF4 is an example of a molecule with a seesaw shape. The axial pair lie along a common bond axis so that are related by a bond angle of 180°. StructureĬompounds with disphenoidal geometry (See-Saw Geometry) have two types of ligands: axial and equatorial. Repulsion by bonding pairs at 120° is much smaller and less important. An equatorial lone pair is repelled by only two bonding pairs at 90°, whereas a hypothetical axial lone pair would be repelled by three bonding pairs at 90° which would make it stable. This is true because the lone pair occupies more space near the central atom (A) than does a bonding pair of electrons. An atom bonded to 5 other atoms (and no lone pairs) forms a trigonal bipyramid with two axial and three equatorial positions, but in the seesaw geometry one of the atoms is replaced by a lone pair of electrons, which is always in an equatorial position. Examples Sulfur tetrafluoride is the premier example of a molecule with the disphenoidal molecular geometry (see image at upper right). The seesaw geometry occurs when a molecule has a steric number of 5, with the central atom being bonded to 4 other atoms and 1 lone pair (AX 4E 1 in AXE notation). Most commonly, four bonds to a central atom result in tetrahedral or, less commonly, square planar geometry. The name "seesaw" comes from the observation that it looks like a playground seesaw. Ideal ax-ax 180°, eq-eq 120°, ax-eq 90° SF 4 ax-ax 173.1°, eq-eq 101.6°ĭisphenoidal or seesaw (also known as sawhorse ) is a type of molecular geometry where there are four bonds to a central atom with overall C 2v molecular symmetry. Structural molecular geometry Seesaw molecular geometry The herbalist is widely known for his wild stories and sense of humor and can always be found either researching new tinctures or asleep at his workbench. This small, cluttered shop is the home and business of Kylos Quarrimac, a former adventurer who gave up a life of wandering in order to become the city’s foremost apothecary and alchemist.
uses an Australian or American credit card, as the value of the good/service is priced in New Zealand Dollars).
Be a Windows Commander! Commands For the Geek In You.Three Tips Tuesday > Part Eight > Three Easy Browser Tips.Wednesday Newsbytes: Free Windows Keys from ChatGPT/Bard Microsoft Updates Windows 11 Requirments AI-Assisted Conspiracy Theories Millions Will Die if Social Media isn’t Overhauled The Most Hacked Passwords – is Yours on This List? AI Predicts Hit Songs with 97% Accuracy … and more!.Create Presentations Quickly and Easily with Presentation GPT.Sandy E on A Simple Tip That Could Speed Up Your Windows 10 or Windows 11 Computer.Dennis L on A Simple Tip That Could Speed Up Your Windows 10 or Windows 11 Computer.on A Simple Tip That Could Speed Up Your Windows 10 or Windows 11 Computer infoave on A Simple Tip That Could Speed Up Your Windows 10 or Windows 11 Computer.Isn’t it a shame that some great programs have to be affiliated with such unethical, money-grubbing “jerks”. I did an advanced uninstall with RevoUninstaller without a second thought. I never did that, and I guess it turned out to be a good thing. I usually wait to “execute” ’til I have time to research it and really spend meaningful time with a program to find out if I like it. Yep, I downloaded it to my desktop and embarrrassed to say….in 2007, and moved it to that “stuff to try later” folder. Cutting to the chase, I found the “execute” file hidden in a file labeled “Stuff to try (spare-time)”. Mine was not a “trial” download ’cause I don’t do “trials” unless somebody I trust (TC) recommends it, so where did it come from? Who recommended that I download it?” Maybe it was bundled with something else? I can’t remember. At first read I said to myself “Hmmm, now where did I hear of Smilebox before? Turns out I downloaded that a long time ago, but never executed it. Many issues with auto-charges and problems with refunds, inability to get customer service to respond:ħ thoughts on “ Smilebox seems to be a box of trouble” YOU AGREE TO SUBSCRIBE TO THEIR NEWSLETTERĬomplaints about not being able to keep them from continuing to charge their credit cards after they quit the service and problems with getting customer service to respond:īeware as they do have a C rating with the BBB (Better Business Bureau) mostly due to what is called improper billing practices: SINCE THEY ALREADY HAVE YOUR CREDIT CARD INFORMATION, YOU MAY NOT EVEN REALIZE YOU ARE GOING TO BE CHARGED WHEN TRING (sic) NEW OFFERS. WHILE A MEMBER, IF THEY OFFER FREE TRIALS OF OTHER THINGS, ONCE THE FREE TRIAL IS OVER YOU ARE AUTOMATICALLY CHARGED, SO BE CAREFUL OF THEIR MANY OFFERS. ONCE PAYMENT IS MADE, NO REFUNDS UNDER ANY CIRCUMSTANCES Several users have complained on download sites like that they were charged before the trial period ended and were unable to obtain a refund.” They offer a 14-day trial period, after which they automatically charge your credit card. You first have to get it to stop running, which is a chore in itself since it seems to have a mind of its own. It wouldn’t uninstall, once I was able to find the uninstall option, because it was running. The program popped up constantly from the system tray asking if I wanted to add the most recent pictures uploaded to my computer to my Smilebox. “I tried SmileBox earlier this year and it took forever to get rid of it. Typical review (after Incredimail purchased): Smilebox has a reputation as the “World’s Most Annoying App”. SmileBox is owned by Incredimail and it seems most complaints are for charging when customer did not expect a charge, refusing to refund, difficulty cancelling, nagware/ads/toolbars, and problems uninstalling. I did not reinstall SmileBox, but would like to use it. It was SuperAntiSpyware that alerted me, so I called them and the tech told me SmileBox is bad, but I know several people who use & enjoy it. It was so cute and I loved the program, but immediately after, my computer crashed with a virus. I downloaded the program about a year ago and made an album. My question is, Is Smilebox safe? I have received some greetings & albums from others and they are so fun. I have learned more from you about computers that from all other sources put together. Thank you both so much for all that you do. |
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